Vanessa Bayeris giving single parenthood a try.

Shes a very globally minded person, and shes a good person.

The two both joined the cast of SNL the same season in 2010.

MARLOW BARKLEY, VANESSA BAYER, IVY PHILBIN, DEVIN TREY CAMPBELL, LEIGHTON MEESTER, TYLER WLADIS, TARAN KILLAM, KIMRIE LEWIS

Kelsey McNeal/ABC

In fact, playing husband and wife was second nature to them in a way.

He makes me laugh more than anyone else.

The role gave Bayer the opportunity to dig into a pretentious approach to living life.

MARLOW BARKLEY, VANESSA BAYER

Kelsey McNeal/ABC

Its very holier than thou.

It was just fun to play.

Which, honestly, it is, she jokingly adds.

TARAN KILLAM, VANESSA BAYER

Kelsey McNeal

The exclusive first photos show Mia at this birthday party, which appears to have a very British theme.

Its interesting for her to be in that world and see what the school is like.

Its more exploring what Will and Sophies life is like now after Ive been away for so long.

VANESSA BAYER, TARAN KILLAM

Kelsey McNeal/ABC

She explains that during their freshman season a sketch required her to kiss Killam.

He has never forgotten that I gagged right in his face.

Hes like a brother to me.

It was kind of what I deserved, she laughs.

I couldnt get through it and I was honestly really trying to.

It was so bizarre and so funny.

I had so much fun doing the show.

Taran makes me laugh more than anybody.

The whole cast is so funny.

It was just a joy to do it.

Single Parentsairs at 9:30 p.m. on ABC.